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Although the researchers could not decrease the size of the sodium ions, they could improve the efficiency with which the sodium ions are inserted into the electrodes. To do this, the researchers used a molecular design strategy based on extending the electrode material's conjugated system, which basically involves manipulating the way that these molecules bond with each other. Physically, this strategy results in a terrace morphology, consisting of multiple, widely spaced layers that form a faster route for the sodium ions to move through. The extended conjugated system also improves the charge transport and stabilizes the charged/discharged states so that they can better tolerate the fast insertion/extraction of Na ions.
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